{"id":13670,"date":"2020-12-10T09:53:31","date_gmt":"2020-12-10T01:53:31","guid":{"rendered":"http:\/\/www.ace-pow.com\/?p=13670"},"modified":"2023-01-03T17:07:05","modified_gmt":"2023-01-03T09:07:05","slug":"%e5%b8%b8%e8%a7%81%e8%81%9a%e5%90%88%e7%89%a9%e9%94%82%e7%94%b5%e6%b1%a0%e5%8f%82%e6%95%b0%e8%ae%a1%e7%ae%97%e5%85%ac%e5%bc%8f","status":"publish","type":"post","link":"http:\/\/www.ace-pow.com\/archives\/13670","title":{"rendered":"\u5e38\u89c1\u805a\u5408\u7269\u9502\u7535\u6c60\u53c2\u6570\u8ba1\u7b97\u516c\u5f0f"},"content":{"rendered":"\n

\u5728\u505a\u805a\u5408\u7269\u9502\u7535\u6c60<\/a>\u751f\u4ea7\u5236\u9020\u6216\u8d2d\u4e70\u7684\u9502\u7535\u6c60\u7684\u65f6\u5019\uff0c\u6211\u4eec\u5e38\u5e38\u4f1a\u7535\u6c60\u7684\u67d0\u4e2a\u53c2\u6570\u9700\u8981\u8fdb\u884c\u8ba1\u7b97\uff0c\u5bf9\u4e8e\u4e0d\u5c11\u4e13\u4e1a\u505a\u9502\u7535\u6c60\u7684\u4eba\u6765\u8bf4\u6bd4\u8f83\u56f0\u96be\uff0c\u4e0b\u9762\u4ecb\u7ecd\u4e00\u4e0b\u5e38\u89c1\u805a\u5408\u7269\u9502\u7535\u6c60\u53c2\u6570\u8ba1\u7b97\u516c\u5f0f\uff0c\u5e0c\u671b\u53ef\u4ee5\u5e2e\u5230\u5927\u5bb6\u3002<\/p>\n\n\n

\n
\"\u5404\u79cd\u5f62\u72b6\u7684\u9502\u7535\u6c60\"<\/figure><\/div>\n\n\n

\uff081\uff09\u9502\u7535\u6c60\u7535\u6781\u6750\u6599\u7684\u7406\u8bba\u5bb9\u91cf\u8ba1\u7b97\u516c\u5f0f<\/p>\n\n\n\n

\u7535\u6781\u6750\u6599\u7406\u8bba\u5bb9\u91cf\uff0c\u5373\u5047\u5b9a\u6750\u6599\u4e2d\u9502\u79bb\u5b50\u5168\u90e8\u53c2\u4e0e\u7535\u5316\u5b66\u53cd\u5e94\u6240\u80fd\u591f\u63d0\u4f9b\u7684\u5bb9\u91cf\uff0c\u5176\u503c\u901a\u8fc7\u4e0b\u5f0f\u8ba1\u7b97\uff1a<\/p>\n\n\n\n

\u6545\u800c\uff0c\u4e3b\u6d41\u7684\u6750\u6599\u7406\u8bba\u5bb9\u91cf\u8ba1\u7b97\u516c\u5f0f\u5982\u4e0b:<\/p>\n\n\n\n

LiFePO4<\/a>\u6469\u5c14\u8d28\u91cf157.756 g\/mol\uff0c\u5176\u7406\u8bba\u5bb9\u91cf\u4e3a\uff1a<\/p>\n\n\n\n

\u540c\u7406\u53ef\u5f97\uff1a\u4e09\u5143\u6750\u6599NCM(1:1:1)(LiNi1\/3Co1\/3Mn1\/3O2 ) \u6469\u5c14\u8d28\u91cf\u4e3a96.461g\/mol\uff0c\u5176\u7406\u8bba\u5bb9\u91cf\u4e3a278 mAh\/g,LiCoO2\u6469\u5c14\u8d28\u91cf97.8698 g\/mol\uff0c\u5982\u679c\u9502\u79bb\u5b50\u5168\u90e8\u8131\u51fa\uff0c\u5176\u7406\u8bba\u514b\u5bb9\u91cf274 mAh\/g.<\/p>\n\n\n\n

\u77f3\u58a8\u8d1f\u6781\u4e2d\uff0c\u9502\u5d4c\u5165\u91cf\u6700\u5927\u65f6\uff0c\u5f62\u6210\u9502\u78b3\u5c42\u95f4\u5316\u5408\u7269\uff0c\u5316\u5b66\u5f0fLiC6\uff0c\u53736\u4e2a\u78b3\u539f\u5b50\u7ed3\u5408\u4e00\u4e2aLi\u30026\u4e2aC\u6469\u5c14\u8d28\u91cf\u4e3a72.066 g\/mol\uff0c\u77f3\u58a8\u7684\u6700\u5927\u7406\u8bba\u5bb9\u91cf\u4e3a\uff1a<\/p>\n\n\n\n

\u5bf9\u4e8e\u7845\u8d1f\u6781\uff0c\u75315Si+22Li++22e- ↔ Li22Si5 \u53ef\u77e5\uff0c 5\u4e2a\u7845\u7684\u6469\u5c14\u8d28\u91cf\u4e3a140.430 g\/mol\uff0c5\u4e2a\u7845\u539f\u5b50\u7ed3\u540822\u4e2aLi\uff0c\u5219\u7845\u8d1f\u6781\u7684\u7406\u8bba\u5bb9\u91cf\u4e3a\uff1a<\/p>\n\n\n\n

\u8fd9\u4e9b\u8ba1\u7b97\u503c\u662f\u7406\u8bba\u7684\u514b\u5bb9\u91cf\uff0c\u4e3a\u4fdd\u8bc1\u6750\u6599\u7ed3\u6784\u53ef\u9006\uff0c\u5b9e\u9645\u9502\u79bb\u5b50\u8131\u5d4c\u7cfb\u6570\u5c0f\u4e8e1\uff0c\u5b9e\u9645\u7684\u6750\u6599\u7684\u514b\u5bb9\u91cf\u4e3a\uff1a\u6750\u6599\u5b9e\u9645\u514b\u5bb9\u91cf=\u9502\u79bb\u5b50\u8131\u5d4c\u7cfb\u6570 \u00d7 \u7406\u8bba\u5bb9\u91cf<\/p>\n\n\n\n

\uff082\uff09\u9502\u7535\u6c60\u8bbe\u8ba1\u5bb9\u91cf\u8ba1\u7b97\u516c\u5f0f<\/p>\n\n\n\n

\u7535\u6c60\u8bbe\u8ba1\u5bb9\u91cf=\u6d82\u5c42\u9762\u5bc6\u5ea6\u00d7\u6d3b\u7269\u8d28\u6bd4\u4f8b\u00d7\u6d3b\u7269\u8d28\u514b\u5bb9\u91cf\u00d7\u6781\u7247\u6d82\u5c42\u9762\u79ef<\/p>\n\n\n\n

\u5176\u4e2d\uff0c\u9762\u5bc6\u5ea6\u662f\u4e00\u4e2a\u5173\u952e\u7684\u8bbe\u8ba1\u53c2\u6570\uff0c\u4e3b\u8981\u5728\u6d82\u5e03\u548c\u8f8a\u538b\u5de5\u5e8f\u63a7\u5236\u3002\u538b\u5b9e\u5bc6\u5ea6\u4e0d\u53d8\u65f6\uff0c\u6d82\u5c42\u9762\u5bc6\u5ea6\u589e\u52a0\u610f\u5473\u7740\u6781\u7247\u539a\u5ea6\u589e\u52a0\uff0c\u7535\u5b50\u4f20\u8f93\u8ddd\u79bb\u589e\u5927\uff0c\u7535\u5b50\u7535\u963b\u589e\u52a0\uff0c\u4f46\u662f\u589e\u52a0\u7a0b\u5ea6\u6709\u9650\u3002\u539a\u6781\u7247\u4e2d\uff0c\u9502\u79bb\u5b50\u5728\u7535\u89e3\u6db2\u4e2d\u7684\u8fc1\u79fb\u963b\u6297\u589e\u52a0\u662f\u5f71\u54cd\u500d\u7387\u7279\u6027\u7684\u4e3b\u8981\u539f\u56e0\uff0c\u8003\u8651\u5230\u5b54\u9699\u7387\u548c\u5b54\u9699\u7684\u66f2\u6298\u8fde\u540c\uff0c\u79bb\u5b50\u5728\u5b54\u9699\u5185\u7684\u8fc1\u79fb\u8ddd\u79bb\u6bd4\u6781\u7247\u539a\u5ea6\u591a\u51fa\u5f88\u591a\u500d\u3002<\/p>\n\n\n\n

\uff083\uff09\u805a\u5408\u7269\u9502\u7535\u6c60\u7684N\/P\u6bd4\u8ba1\u7b97\u516c\u5f0f<\/p>\n\n\n\n

\u8d1f\u6781\u6d3b\u6027\u7269\u8d28\u514b\u5bb9\u91cf\u00d7\u8d1f\u6781\u9762\u5bc6\u5ea6\u00d7\u8d1f\u6781\u6d3b\u6027\u7269\u542b\u91cf\u6bd4\u00f7\uff08\u6b63\u6781\u6d3b\u6027\u7269\u8d28\u514b\u5bb9\u91cf\u00d7\u6b63\u6781\u9762\u5bc6\u5ea6\u00d7\u6b63\u6781\u6d3b\u6027\u7269\u542b\u91cf\u6bd4\uff09<\/p>\n\n\n\n

\u77f3\u58a8\u8d1f\u6781\u7c7b\u7535\u6c60N\/P\u8981\u5927\u4e8e1.0\uff0c\u4e00\u822c1.04~1.20\uff0c\u8fd9\u4e3b\u8981\u662f\u51fa\u4e8e\u5b89\u5168\u8bbe\u8ba1\uff0c\u4e3b\u8981\u4e3a\u4e86\u9632\u6b62\u8d1f\u6781\u6790\u9502\uff0c\u8bbe\u8ba1\u65f6\u8981\u8003\u8651\u5de5\u5e8f\u80fd\u529b\uff0c\u5982\u6d82\u5e03\u504f\u5dee\u3002\u4f46\u662f\uff0cN\/P\u8fc7\u5927\u65f6\uff0c\u7535\u6c60\u4e0d\u53ef\u9006\u5bb9\u91cf\u635f\u5931\uff0c\u5bfc\u81f4\u7535\u6c60\u5bb9\u91cf\u504f\u4f4e\uff0c\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\u4e5f\u4f1a\u964d\u4f4e\u3002<\/p>\n\n\n\n

\u800c\u5bf9\u4e8e\u949b\u9178\u9502\u8d1f\u6781\uff0c\u91c7\u7528\u6b63\u6781\u8fc7\u91cf\u8bbe\u8ba1\uff0c\u7535\u6c60\u5bb9\u91cf\u7531\u949b\u9178\u9502\u8d1f\u6781\u7684\u5bb9\u91cf\u786e\u5b9a\u3002\u6b63\u6781\u8fc7\u91cf\u8bbe\u8ba1\u6709\u5229\u4e8e\u63d0\u5347\u7535\u6c60\u7684\u9ad8\u6e29\u6027\u80fd\uff1a\u9ad8\u6e29\u6c14\u4f53\u4e3b\u8981\u6765\u6e90\u4e8e\u8d1f\u6781\uff0c\u5728\u6b63\u6781\u8fc7\u91cf\u8bbe\u8ba1\u65f6\uff0c\u8d1f\u6781\u7535\u4f4d\u8f83\u4f4e\uff0c\u66f4\u6613\u4e8e\u5728\u949b\u9178\u9502\u8868\u9762\u5f62\u6210SEI\u819c\u3002<\/p>\n\n\n\n

\uff084\uff09\u9502\u7535\u6c60\u751f\u4ea7\u6d82\u5c42\u7684\u538b\u5b9e\u5bc6\u5ea6\u53ca\u5b54\u9699\u7387\u8ba1\u7b97\u516c\u5f0f<\/p>\n\n\n\n

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\u800c\u8003\u8651\u5230\u6781\u7247\u8f8a\u538b\u65f6\uff0c\u91d1\u5c5e\u7b94\u6750\u5b58\u5728\u5ef6\u5c55\uff0c\u8f8a\u538b\u540e\u6d82\u5c42\u7684\u9762\u5bc6\u5ea6\u901a\u8fc7\u4e0b\u5f0f\u8ba1\u7b97\uff1a<\/p>\n\n\n\n

\u6d82\u5c42\u7531\u6d3b\u7269\u8d28\u76f8\u3001\u78b3\u80f6\u76f8\u548c\u5b54\u9699\u7ec4\u6210\uff0c\u5b54\u9699\u7387\u8ba1\u7b97\u516c\u5f0f\uff1a<\/p>\n\n\n\n

\u5176\u4e2d\uff0c\u6d82\u5c42\u7684\u5e73\u5747\u5bc6\u5ea6\u4e3a\uff1a<\/p>\n\n\n\n

\uff085\uff09\u7535\u6c60\u7684\u9996\u6548\u8ba1\u7b97\u516c\u5f0f<\/p>\n\n\n\n

\u9996\u6548=\u9996\u6b21\u653e\u7535\u5bb9\u91cf\/\u9996\u6b21\u5145\u7535\u5bb9\u91cf<\/p>\n\n\n\n

\u65e5\u5e38\u751f\u4ea7\u4e2d\uff0c\u4e00\u822c\u662f\u5148\u5316\u6210\u518d\u8fdb\u884c\u5206\u5bb9\uff0c\u5316\u6210\u5145\u5165\u4e00\u90e8\u5206\u7535\uff0c\u5206\u5bb9\u8865\u5145\u7535\u540e\u518d\u653e\u7535\uff0c\u6545\u800c\uff1a<\/p>\n\n\n\n

\u9996\u6548=\uff08\u5316\u6210\u5145\u5165\u5bb9\u91cf+\u5206\u5bb9\u8865\u5145\u7535\u5bb9\u91cf\uff09\/\u5206\u5bb9\u7b2c\u4e00\u6b21\u653e\u7535\u5bb9\u91cf<\/p>\n\n\n\n

\uff086\uff09\u80fd\u91cf\u5bc6\u5ea6\u8ba1\u7b97\u516c\u5f0f<\/p>\n\n\n\n

\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6(Wh\/L)=\u7535\u6c60\u5bb9\u91cf(mAh)\u00d73.6(V)\/\uff08\u539a\u5ea6(cm)*\u5bbd\u5ea6(cm)*\u957f\u5ea6(cm)\uff09 \u8d28\u91cf\u80fd\u91cf\u5bc6\u5ea6(Wh\/KG)=\u7535\u6c60\u5bb9\u91cf(mAh)\u00d73.6(V)\/\u7535\u6c60\u91cd\u91cf<\/p>\n\n\n\n

\u4e0a\u9762\u5c31\u662f\u5173\u4e8e\u805a\u5408\u7269\u9502\u7535\u6c60\u5e38\u89c1\u53c2\u6570\u7684\u51e0\u4e2a\u8ba1\u7b97\u516c\u5f0f\uff0c\u662f\u6bd4\u8f83\u65b9\u4fbf\u7684\u7406\u8bba\u8ba1\u7b97\u503c\uff0c\u53ef\u4ee5\u5f88\u597d\u5730\u5e2e\u52a9\u5927\u5bb6\u76f8\u5bf9\u8f83\u5feb\u7684\u67e5\u770b\u9502\u7535\u6c60\u5382\u5bb6<\/a>\u63d0\u4f9b\u7684\u7535\u6c60\u4ea7\u54c1\u662f\u5426\u7b26\u5408\u81ea\u5df1\u7684\u9700\u6c42\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5728\u505a\u805a\u5408\u7269\u9502\u7535\u6c60\u751f\u4ea7\u5236\u9020\u6216\u8d2d\u4e70\u7684\u9502\u7535\u6c60\u7684\u65f6\u5019\uff0c\u6211\u4eec\u5e38\u5e38\u4f1a\u7535\u6c60\u7684\u67d0\u4e2a\u53c2\u6570\u9700\u8981\u8fdb\u884c\u8ba1\u7b97\uff0c\u5bf9\u4e8e\u4e0d\u5c11\u4e13\u4e1a\u505a\u9502\u7535\u6c60\u7684\u4eba\u6765\u8bf4\u6bd4\u8f83\u56f0\u96be\uff0c\u4e0b\u9762\u4ecb\u7ecd\u4e00\u4e0b\u5e38\u89c1\u805a\u5408\u7269\u9502\u7535\u6c60\u53c2\u6570\u8ba1\u7b97\u516c\u5f0f\uff0c\u5e0c\u671b\u53ef\u4ee5\u5e2e\u5230\u5927\u5bb6\u3002 \uff081\uff09\u9502\u7535\u6c60\u7535\u6781\u6750\u6599\u7684\u7406\u8bba\u5bb9\u91cf\u8ba1\u7b97\u516c\u5f0f \u7535\u6781\u6750\u6599\u7406\u8bba\u5bb9\u91cf\uff0c\u5373\u5047\u5b9a\u6750\u6599\u4e2d\u9502\u79bb\u5b50\u5168\u90e8\u53c2\u4e0e\u7535\u5316\u5b66\u53cd\u5e94\u6240\u80fd\u591f\u63d0\u4f9b\u7684\u5bb9\u91cf\uff0c\u5176\u503c\u901a\u8fc7\u4e0b\u5f0f\u8ba1\u7b97\uff1a \u6545\u800c\uff0c\u4e3b\u6d41\u7684\u6750\u6599\u7406\u8bba\u5bb9\u91cf\u8ba1\u7b97\u516c\u5f0f\u5982\u4e0b: LiFePO4\u6469\u5c14\u8d28\u91cf157.756 g\/mol\uff0c\u5176\u7406\u8bba\u5bb9\u91cf\u4e3a\uff1a \u540c\u7406\u53ef\u5f97\uff1a\u4e09\u5143\u6750\u6599NCM(1:1:1)(LiNi1\/3Co1\/3Mn1\/3O2 ) \u6469\u5c14\u8d28\u91cf\u4e3a96.461g\/mol\uff0c\u5176\u7406\u8bba\u5bb9\u91cf\u4e3a278 mAh\/g,LiCoO2\u6469\u5c14\u8d28\u91cf97.8698 g\/mol\uff0c\u5982\u679c\u9502\u79bb\u5b50\u5168\u90e8\u8131\u51fa\uff0c\u5176\u7406\u8bba\u514b\u5bb9\u91cf274 mAh\/g. \u77f3\u58a8\u8d1f\u6781\u4e2d\uff0c\u9502\u5d4c\u5165\u91cf\u6700\u5927\u65f6\uff0c\u5f62\u6210\u9502\u78b3\u5c42\u95f4\u5316\u5408\u7269\uff0c\u5316\u5b66\u5f0fLiC6\uff0c\u53736\u4e2a\u78b3\u539f\u5b50\u7ed3\u5408\u4e00\u4e2aLi\u30026\u4e2aC\u6469\u5c14\u8d28\u91cf\u4e3a72.066 g\/mol\uff0c\u77f3\u58a8\u7684\u6700\u5927\u7406\u8bba\u5bb9\u91cf\u4e3a\uff1a \u5bf9\u4e8e\u7845\u8d1f\u6781\uff0c\u75315Si+22Li++22e- ↔ Li22Si5 \u53ef\u77e5\uff0c 5\u4e2a\u7845\u7684\u6469\u5c14\u8d28\u91cf\u4e3a140.430 g\/mol\uff0c5\u4e2a\u7845\u539f\u5b50\u7ed3\u540822\u4e2aLi\uff0c\u5219\u7845\u8d1f\u6781\u7684\u7406\u8bba\u5bb9\u91cf\u4e3a\uff1a \u8fd9\u4e9b\u8ba1\u7b97\u503c\u662f\u7406\u8bba\u7684\u514b\u5bb9\u91cf\uff0c\u4e3a\u4fdd\u8bc1\u6750\u6599\u7ed3\u6784\u53ef\u9006\uff0c\u5b9e\u9645\u9502\u79bb\u5b50\u8131\u5d4c\u7cfb\u6570\u5c0f\u4e8e1\uff0c\u5b9e\u9645\u7684\u6750\u6599\u7684\u514b\u5bb9\u91cf\u4e3a\uff1a\u6750\u6599\u5b9e\u9645\u514b\u5bb9\u91cf=\u9502\u79bb\u5b50\u8131\u5d4c\u7cfb\u6570 \u00d7 \u7406\u8bba\u5bb9\u91cf \uff082\uff09\u9502\u7535\u6c60\u8bbe\u8ba1\u5bb9\u91cf\u8ba1\u7b97\u516c\u5f0f \u7535\u6c60\u8bbe\u8ba1\u5bb9\u91cf=\u6d82\u5c42\u9762\u5bc6\u5ea6\u00d7\u6d3b\u7269\u8d28\u6bd4\u4f8b\u00d7\u6d3b\u7269\u8d28\u514b\u5bb9\u91cf\u00d7\u6781\u7247\u6d82\u5c42\u9762\u79ef \u5176\u4e2d\uff0c\u9762\u5bc6\u5ea6\u662f\u4e00\u4e2a\u5173\u952e\u7684\u8bbe\u8ba1\u53c2\u6570\uff0c\u4e3b\u8981\u5728\u6d82\u5e03\u548c\u8f8a\u538b\u5de5\u5e8f\u63a7\u5236\u3002\u538b\u5b9e\u5bc6\u5ea6\u4e0d\u53d8\u65f6\uff0c\u6d82\u5c42\u9762\u5bc6\u5ea6\u589e\u52a0\u610f\u5473\u7740\u6781\u7247\u539a\u5ea6\u589e\u52a0\uff0c\u7535\u5b50\u4f20\u8f93\u8ddd\u79bb\u589e\u5927\uff0c\u7535\u5b50\u7535\u963b\u589e\u52a0\uff0c\u4f46\u662f\u589e\u52a0\u7a0b […]<\/p>\n","protected":false},"author":3720,"featured_media":13124,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[178],"tags":[],"_links":{"self":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts\/13670"}],"collection":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/users\/3720"}],"replies":[{"embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/comments?post=13670"}],"version-history":[{"count":2,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts\/13670\/revisions"}],"predecessor-version":[{"id":18875,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/posts\/13670\/revisions\/18875"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/media\/13124"}],"wp:attachment":[{"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/media?parent=13670"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/categories?post=13670"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.ace-pow.com\/wp-json\/wp\/v2\/tags?post=13670"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}